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Pulse of the Planet: Can’t Turn Down the Heat

Imagine you’re in the shower and you turn up the hot water, but it gets too hot – scalding hot. What do you do? Turn the hot water down, of course. But what if you can’t? And what if you can’t even get out of the shower? You’d probably regret having turned up the hot water tap. A new paper shows that that kind of scenario is what we're facing in the case of global warming.

Since preindustrial times, carbon dioxide (CO2) concentrations have increased from about 280 parts per million (ppm) to a little more than 385 ppm. Scientists have shown that much of this increase has resulted from the burning of fossil fuels. How have they reached this conclusion? In a variety of ways. Isotopes are one.

What Carbon-13 Tells Us About Atmospheric CO2

Remember protons and neutrons? It’s the stuff the centers (or nuclei) of atoms are made of. The number of protons determines what kind of atom it is. For example, carbon has six protons. Any atom with six protons is carbon, regardless of the number of neutrons. Almost 99 percent of the carbon on Earth is carbon-12 – it has six protons and six neutrons. About one percent is carbon-13 with six protons and seven neutrons.

The carbon in fossil fuels is made up of less C-13 than the CO2 in the atmosphere. As a result, one would expect that as fossil fuels are burned and the C-13-poor carbon in fossil fuels is converted into atmospheric CO2, the C-13 abundance in atmospheric CO2 would decline. And that is in fact exactly what is observed (see graphic). The conclusion: burning fossil fuels is increasing atmospheric CO2 concentrations.

Monthly C-13 at Mauna Loa, Hawaii (1980-2002)
Changes in the relative abundance of C-13 in the atmosphere as reported by Oak Ridge National Lab’s Carbon Dioxide Information Analysis Center. Note: the more negative the numbers plotted on the left, the lower the relative abundance of C-13.

 It is now well-established that the increase in atmospheric CO2 has already begun to disrupt the climate. In addition to rising average global temperatures, we are seeing melting glaciers, as well as melting sea ice, worrisome trends in rainfall with increasing variability favoring floods and droughts, rising sea levels, more wildfires, and dying forests.

At the same time this is occurring, global emissions of CO2 have been increasing by about two percent a year. (That rate has undoubtedly slowed or maybe even reversed as a result of the global economic downturn, but will probably resume once the economy gets back in gear.) Increasing emissions lead to increasing CO2 concentration and more climate disruption.

How to Fix the Problem?

What’s to be done? One approach is the one we often take in the shower. We turn up the hot water until it gets too hot and then turn it back down. In the case of climate change that would translate into continuing to emit CO2 until the disruption gets so bad that we then just turn off the spigot – that is, we stop emitting CO2 and let the climate cool. Right? Wrong. As shown by Susan Solomon of NOAA’s Earth Systems Research Laboratory and her colleagues in the Proceedings of the National Academy of Sciences, it will take more than 1,000 years for the climate to cool back to where we started in preindustrial times.

I have known Susan Solomon since the 1970s when she was a graduate student working with Paul Crutzen, winner of the 1995 Nobel Prize in Chemistry for his work on stratospheric ozone depletion.  In the 1980s Susan traveled to the Antarctic where she made the critical measurements showing that the Antarctic ozone hole was caused by reactions involving chlorine atoms from the breakdown of chorofluorocarbons. For that work, Susan was cited in the 1995 Nobel Prize presentation speech to Sherwood Rowland, Mario Molina, and Crutzen.

More recently Susan was the chairman of the Intergovernmental Panel on Climate Change’s Working Group 1 – the team charged with assessing the state of the science of the physical climate system. The group’s work was an arduous process: establishing a consensus among a broad spectrum of scientists and then, once the report was written to reflect that consensus, responding to literally hundreds of comments from peer reviewers.

Global Warming Is Forever

Now, Susan along with her colleagues has added to her impressive record with this new work showing in stark terms the consequences of waiting to act on climate change - for all intents and purposes, global warming is “forever.” There are two reasons and both arise from the slow mixing of the surface ocean with the deep ocean:

  1. When CO2 is emitted into the atmosphere, about half of it is almost immediately removed and added to the surface ocean and to forests. The remaining half, called the airborne fraction, stays in the atmosphere for many hundreds of years awaiting the very slow transfer to the surface ocean and then into the deep ocean. So even if we stopped emitting CO2 today, it would take centuries on centuries (about 1,000 years), before CO2 concentrations would approach that of preindustrial times.
  2. One might expect that as CO2 decreases (albeit slowly) from a cessation of CO2 emissions, at least the climate would slowly cool, but it doesn’t. Some of the warming from the increased CO2 has been stored in the ocean, and as CO2 decreases this excess heat is slowly released from the ocean keeping temperatures elevated for a thousand years or so.

A thousand years is a long time to wait to cool down. Do we really want to keep turning up the hot water?

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Fossil fuel CO2

Posted by Ken Towe at Oct 26, 2009 10:08 AM
Bill writes: "The carbon in fossil fuels is made up of less C-13 than the CO2 in the atmosphere. As a result, one would expect that as fossil fuels are burned and the C-13-poor carbon in fossil fuels is converted into atmospheric CO2, the C-13 abundance in atmospheric CO2 would decline. And that is in fact exactly what is observed (see graphic). The conclusion: burning fossil fuels is increasing atmospheric CO2 concentrations." .....followed by:
"When CO2 is emitted into the atmosphere, about half of it is almost immediately removed and added to the surface ocean and to forests. The remaining half, called the airborne fraction, stays in the atmosphere for many hundreds of years..."

Bill: Not sure where "about half" comes from, but assigning "the remaining half" to a fossil fuel origin is too large. The carbon isotope chart in your graphic reveals that median C-13 decreased from about -7.6 permil in 1981 to about -8.0 permil in 2002. Over the same period of time Mauna Loa total CO2 increased from about 340 ppmv to 373 ppmv, an increase of 33 ppmv or 9.71%. The average C-13 value for fossil fuel CO2 is about -27 permil. If 50% of the added CO2 is from fossil fuels the C-13 ratio in 2002 should have been closer to -9.0 than to -8.0. Calculation: .0971 x -27 = -2.62 permil. Half of this is -1.31. Add this to -7.6 yields -8.91 for 2002. The true value, if "about -27" is correct, should be about 15%, not 50%. Thus, only 15% of fossil fuel-derived CO2 is the airborne fraction, not about half...big difference.

Dr. Chameides responds -

Posted by Erica Rowell (Editor) at Nov 04, 2009 12:53 PM
Ken, You do not appear to understand the relationship between changes in the atmospheric C-13/C-12 ratio (del C13) and its sources; it's just not as simple as you appear to think.

The change in atmospheric del C13 is influenced not only by the addition of isotopically light fossil-fuel CO2 emissions, but also by fractionation associated with net atmosphere-land and atmosphere-ocean fluxes, as well as by the change of del C13 associated with gross fluxes (i.e., del C13 can change even when the net C12 flux is zero). For more info, see equations 1 and 5 in Battle et al., Science, 2467-2470. http://www.sciencemag.org/[…]/2467

Isotopically "light" CO2

Posted by Ken Towe at Nov 09, 2009 01:29 PM
Bill: My simple understanding has been that the annual values for both CO2 and del C-13 are mid-monthly mean values and as such they represent the net result of all of the many complex interannual, seasonal, diurnal and other influences, as shown in your monthly C-13 chart and in a typical monthly Keeling CO2 chart. In 1850 the annual mean was around 280 ppmv CO2 with a mean C-13 value near -6.5 ...both all natural. With increasing isotopically "light" anthropogenic input, by 2000 total CO2 had risen year-by-year to a mean 369.41 ppmv* and, as expected, the mean atmospheric C-13 had gotten isotopically lighter, decreasing year-by-year to -8.049 per mil* (2000). Geographic variability is minimized because both were measured and averaged annually at Mauna Loa.

Question: By the year 2000 how many ppmv of added and admixed isotopically light anthropogenic CO2 (C-13 ± -27 per mil) are necessary to account for the change in the average annual atmospheric C-13 at Mauna Loa since 1850 from -6.5 per mil to -8.049 per mil? There should be only one answer?

*CO2 Source: http://cdiac.ornl.gov/ftp/trends/co2/maunaloa.co2
*C-13 Source: http://cdiac.esd.ornl.gov/ftp/trends/co2/iso-sio/mlo.dat

Dr. Chameides responds -

Posted by Erica Rowell (Editor) at Nov 10, 2009 03:23 PM
Ken, The question is framed incorrectly. It seems to assume implicitly that the change in atmospheric del-C13 from preindustrial to present is due only to the addition of isotopically light fossil-fuel CO2 emissions. This assumption is incorrect -- to correctly interpret the change in atmospheric C13, one also has to account for atmosphere-ocean and atmosphere-land CO2 fluxes that cause isotopic fractionation.

Anthropogenic CO2

Posted by Ken Towe at Nov 13, 2009 09:05 AM
Bill.. You're right. It cannot be fossil fuel emissions ONLY since those from land-use changes (deforestation) and natural recycling would be included as well. The question was framed to calculate just the fraction of CO2 with del C-13 = -27 (usually ascribed primarily to fossil fuels) present in the atmosphere. Del -27 will, necessarily, include part of the land-use fraction...the CO2 from biomass burning and loss of C3 forests. It will not include CO2 from the loss or burning of C4 plants (e.g., grasses, maize) which are much heavier, averaging ~ -12.5 per mil. To this extent, the numbers derived from a C-13 analysis (~18-20%; 66-75 ppmv) will be larger than those derived by the CDIAC (~14%, 52 ppmv) which did not include land-use CO2. Calculations from the CDIAC estimates for land-use CO2 remaining in the atmosphere would be ~7% (25 ppmv). A total anthropogenic CO2 percentage for the year 2000 would then be ~21% of the world total, or ~77 ppmv. Of course, the percentage of each in the CO2 added since pre-industrial times remains ~64% and ~35% respectively. Thus, the total CO2 in the atmosphere had risen by ~28% (to the year 2000) but the anthropogenic fraction rose by ~21%, leaving 7% to be accounted for? If this is incorrect what would be the correctly interpreted value for the amounts of CO2 derived from fossil fuels (ppmv) and land-use changes (ppmv) that will be consistent with the C-13 changes depicted in the CDIAC chart?

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Dean Chameides

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